Hitran2012 database, supporting the claim that the majority of line in. Integrated band intensities of ethylene 1 2 2 4 by. This database is an atlas of molecular spectra and associated tables of wavenumbers from heterodyne frequency measurements for the calibration of infrared spectrometers. Abstract this paper describes the status of the 2008 edition of the hitran molecular spectroscopic database. Pdf the hitran2012 molecular spectroscopic database. The new edition replaces the previous hitran edition of 2012 and its updates during the. To synthesize the datasets, firstly, single gas molecule midinfrared absorption crosssection spectra of c 2 h 6, c h 4, c o, h 2 o, h b r, h c l, h f, n 2 o, and n o measured at 296 k were selected from the high. The input power of a co 2 microwave plasma is modulated at khz rate in scans of duty cycle at constant average power to investigate gas heating dynamics and its relation to dissociation efficiency.
A graph g, corresponding to an sn of a molecule, say h 2 16 o, is an ordered pair, g l,t, where l is the set of energy levels vertices and t is a set of transitions edges, the. The improvements for nh3 in the hitran 2000, containing some 29084. Gamache, michael rey, bastien vispoel, vladimir tyuterev, reduced matrix elements for collisionally induced transitions of 12 ch 4, submitted to j. The splatalogue is an attempt to collate, rationalize and extend existing spectroscopic resources for use by the astronomical community. Ontologybased content trust support of expert information. The hitran molecular spectroscopic database and hawks hitran. Currently, splatalogue is a transitionresolved compilation of the jpl, cdms and lovasnist lists searching 3688088 lines in 656 chemical species. The jpl molecular spectroscopy team supports nasa programs in astrophysics, atmospheric science, and planetary science. Many new spectroscopic phenomena are now available for.
Hitran is an acronym for highresolution transmission molecular absorption database. Hitran is a compilation of spectroscopic parameters that a variety of. Atomic spectroscopy intro outlines basic atomic physics concepts, explains terminology and notation. Additional information about the database may be obtained through the following links. New data on the intensities and line positions in the 1 2 band of 12 c 2 h 4 as reported by rotger et al.
Why are methane spectroscopic parameters harder to. We present a comprehensive spectroscopic line list for methane containing almost 10 billion transitions, 2,000 times more than any previous compilation, covering a broad. Please dont hesitate to get in touch using the contact link in the bottom right. The hitran2012 molecular spectroscopic database, journal of.
The hitran database hitranis an acronym for highresolution transmission molecular absorption database. The new edition replaces the previous hitran edition. Alternative updates of both hitran 2008, 2012 and geisa 2011, 2015 databases give to the users the possibility to have the best spectroscopic parameters at any time table 1 study of the residuals. Hitran 2012 refractive indices, journal of quantitative. A homemade software using the hitran 2012 database rothman et al. Hitran pc is a commercial software product for laser remote sensing of the atmosphere that uses the hitran, epa, or pnnl databases to calculate highresolution molecular absorption and aerosol attenuation for horizontal or slant paths, different atmospheric models, and gas plume geometries. The importance of thermal dissociation in co2 microwave. This edition replaced the earlier version, hitran, hawks and hitemp.
This paper describes the status of the latest edition of the hitran molecular spectroscopic. From a theoretical standpoint it can take years to construct a comprehensive line list suitable for highresolution spectroscopy. The hitran2016 molecular spectroscopic database centaur. There is a pressing need for an accurate and complete spectroscopic database for methane at elevated temperatures. The hitemp2010 database is described in the article hitemp, the hightemperature molecular spectroscopic database 2010.
The line parameters of ammonia and phosphine have been revised using new results for line positions, intensities and line widths. The new edition replaces the previous hitran edition of 2008 and its updates during the intervening years. The majority of entries in the 2012 version of the hitran database were taken from. Gestion et etude des informations spectroscopiques. The hitran2012 molecular spectroscopic database article in journal of quantitative spectroscopy and radiative transfer. This paper describes the status of the 2008 edition of the hitran molecular spectroscopic database.
Absorption simulations are performed using the hitran 2012 and hitemp 2010 databases. Hitran is a compilation of spectroscopic parameters that a variety of computer codes use to predict and simulate the transmission and emission of light in the atmosphere. This paper describes the status of the 2012 edition of the hitran molecular spectroscopic compilation. Hitran is a compilation of spectroscopic parameters that a variety of computer codes use to predict and simulate. Vpl molecular spectroscopic database this is a collection of line list and absorption crosssection images for molecules of interest to the vpl. The hitran2012 molecular spectroscopic database, journal. Abstract this paper describes the status of the 2012 edition of the hitran molecular spectroscopic compilation.
Hitran the hitran an acronym for high resolution transmission molecular spectroscopic database is a compilation of spectroscopic parameters used to simulate and analyze the transmission and emission of light in gaseous media, with an emphasis on planetary atmospheres. Information on hitran and hitemp can be found here. The hitran2012 molecular spectroscopic database harvard cfa. A new relational database structure and online interface for. The hitran 2008 molecular spectroscopic database nasa. The hitran molecular database, the eighth international conference on atomic and molecular data and their applications, gaithersburg md, usa october 2012 invited. Jul 01, 2014 hot methane is important in cool stars, brown dwarfs, exoplanets, gas turbine engines, and elsewhere.
Hitran is recognized as the international standard of the fundamental spectroscopic parameters for diverse. An approach to assessing the content trust of information resources based on a publishing criterion has been developed and applied to several tens of spectroscopic expert datasets. Nineteen ninetyeight marks the 25th anniversary of the release of the first hitran database. Hitran database hitran is an acronym for highresolution transmission molecular absorption database. Partition functions qt of the 17 o c 17 o molecule are added to the database in the temperature range 1 k calculation by s. Spectrum of hot methane in astronomical objects using a. The hitran 2012 molecular spectroscopic database, journal of quantitative spectroscopy and radiative transfer, 450 20. The hitran2012 molecular spectroscopic database esd. Bytran is based in part on the hitran application programming interface hapi source code and relies on data provided in the online version of the highresolution transmission molecular. Actual data can be made available upon request depending on the source, and each molecule may have available data from several different sources. The new edition is meant to replace the previous hitran edition of 2008 and its updates during the intervening years. Bytran spectral calculations for portable devices using. The hitran 2012 molecular spectroscopic database l. Geisa a computeraccessible spectroscopic database and associated management software, designed for the interpretation of remote sensing observations suitable for all instrument categories and using.
Hitran now includes a large number of molecules and their isotopologues. Hitran is the worldwide standard for calculating or simulating atmospheric molecular transmission and radiance from the microwave through ultraviolet region of the spectrum. Before sharing sensitive information, make sure youre on a federal government site. To synthesize the datasets, firstly, single gas molecule midinfrared absorption crosssection spectra of c 2 h 6, c h 4, c o, h 2 o, h b r, h c l, h f, n 2 o, and n o measured at 296 k were selected from the highresolution transmission molecular absorption hitran database and are displayed in figure 1a. Parameters for broadening of o 2 by h 2 o come from the study. The hitran molecular spectroscopic database and hawks. Hitran is recognized as the international standard of the fundamental spectroscopic parameters for diverse atmospheric and laboratory transmission and radiance calculations. Hitemp simulations take much longer to run than hitran simulations, so please choose your simulation window wisely. The hitran2016 molecular spectroscopic database journal. Hitran spectroscopic database abstract this paper describes the status of the 2012 edition of the hitran molecular spectroscopic compilation. Updated database plus software for linemixing in co2 infrared spectra and.
The hitran 2008 molecular spectroscopic database, journal of. Co2 line mixing database and software below one can downlaod the 2010 hitran co 2 database with line mixing included and codes to calculate the absorption coefficient including line mixing according. This paper describes the status of the latest edition of the hitran molecular spectroscopic compilation. The hitran2016 molecular spectroscopic database sciencedirect. Hitran is a compilation of spectroscopic parameters which a variety of computer codes. The core information for this publications citation rothman, l. The hitran2012 molecular spectroscopic database nasa. Its activities include measurement of rotational lines, fitting the lines, and preparing a catalog of line positions and intensities. The geisa spectroscopic database 2015 edition in the frame. The new edition is the first official public release since the 2004 edition, although a number of crucial updates had been made available online since 2004. The hitran2012 molecular spectroscopic database sciencedirect. In this context, the absorption parameters of gas molecules absorption crosssection and line intensity at specified pressures and temperatures are tabulated using spectroscopic databases such as. Simulating electric field interactions with polar molecules. Hitran is now applicable to planetary atmospheres in addition to terrestrial.
The improvements for nh3 in the hitran 2000, containing some 29084 lines corresponding to more than twice the number of lines present in the 1996 hitran database for this molecule involved replacing purerotational and infrared transitions from 0 to 5294 cm1 with. The current version, hitran2016, contains 49 molecules in the linebyline portion of hitran and with their respective isotopologues, totaling in at 126 isotopologues of line by line molecules. Hitran the hitran molecular spectroscopic database is a compilation of spectroscopic. Room temperature line lists for co\2 symmetric isotopologues with. The hitran 2008 molecular spectroscopic database research. We examine the question of whether the shortwave forcing of ch 4 is affected by recent andor future additions to our tabulations of its absorption band structure. The hitran2016 molecular spectroscopic database request pdf. The hitran2012 molecular spectroscopic database request pdf. The article documenting the 2012 hitran spectroscopic database update rothman et al. The hitran molecular absorption compilation is comprised of five major components.
The new edition replaces the previous hitran edition of 2012 and its updates during the intervening years. The updates 2018 of the hitran database for h 2 o, co 2, no and cocl 2 are now available. This paper describes the contents of the 2016 edition of the hitran molecular spectroscopic compilation. Note that the 727 isotope of co2 is now isotope 9 and the 838 isotope has been removed due to limit of 9 isotopes in the current version of spectralcalc. Highresolution spectroscopy of methane and the generation of accurate line lists, especially as one. This article describes the data and software that have been added, modified, or enhanced. A collisional database repository and web service within vamdc m. Hitemp simulations take much longer to run than hitran. A new edition of the hitran molecular spectroscopic database is described. Chemometric approach to the calibration of light emitting. N2 this paper describes the status of the 2008 edition of the hitran molecular spectroscopic database. A considerable amount of work goes into creating and maintaining spectroscopic databases 10,11,12,14,15,16,17 and they contain a wealth of molecular information. Simple molecules as complex systems pubmed central pmc. Hitran2016 molecular spectroscopic database is described.
1224 1572 346 486 105 150 700 420 87 1025 623 1011 1255 1096 128 1460 1371 1082 1512 457 958 1527 13 1048 361 653 1087 271 1183 211 842 870 432 1088 556 717 1226 511 464 648 232 662 17